AYRIM BESH A’ZOLI BIAZOSIKLIK BIRIKMALARNING HOSILALARI SINTEZI VA XOSSALARI

Mualliflar

DOI:

https://doi.org/10.5281/zenodo.19629316

Kalit so‘zlar:

imidazolinlar, uch atomli kislota fraksiyasi, yog‘ kislotalari, korroziya ingibitori, diamidlar, neft ishlab chiqarish, ekologik barqarorlik

Abstrak

Tadqiqotlar davomida yog‘och qipig‘ini adsorbsiyalab va izopropil spirtida ekstraksiyalab olingan uch kislotali fraksiyadan (FTK) 2-geksadetsil-2-imidozolin C20H40N2, 2-oktadetsil-2-imidozolin C21H40N2 va 2-oktadetsenil-2-imidozolin C21H38N2 sintez qilishning maqbul sharoitlari aniqlandi. Sintez uchun 98% etilendiamin ishlatilgan. FTK mos ravishda 30,3+22,7+42,3% massa nisbatda bo‘lgan palmitin, olein va linol kislotalarining aralashmasidan iborat.

Muallif biografiyalari

  • Yulduz Usmonova, Doctor of Philosophy in Chemical Sciences (PhD)

    Senior Lecturer of the Department of "Technology of Organic Synthesis" of the Tashkent Chemical-Technological Institute

  • Khasan Kadirov, Doctor of Technical Sciences

    Professor of the Department of "Technology of Organic Synthesis" of the Tashkent Chemical-Technological Institute

  • Jazira Nurmanova

    Master of the Department of "Technology of Organic Synthesis" of the Tashkent Chemical-Technological Institute

  • Shoyunus Obidov, Doctor of Philosophy in Technical Sciences (PhD)

    Senior Lecturer of the Department of "Technology of Organic Synthesis" of the Tashkent Chemical-Technological Institute

Havolalar

Lopez D.A., Perez T., Simison S.N. The influence of microstructure and chemical composition of carbon and low alloy steels in CO2 corrosion. A state- of-the-art appraisal Materials & Design. 2003, vol. 24. №. 8, 561-575.

L.A. Abukova, O.P. Abramova, A.V. Koshelev. Isxodniy sostav plastovix vod kak osnova gidrogeoximicheskogo kontrolya za razrabotkoy achimovskix otlojeniy Urengoyskogo NGKM [The initial composition of reservoir waters as the basis for hydrogeochemical control over the development of the Achimov deposits of the Urengoy NGKM]. Prioritetniye napravleniya razvitiya Urengoyskogo kompleksa: Sbornik nauchnыx trudov. Moskva: Izdatelstvo «Nedra», 2013, 171-180.

Usmonova Yu.Sh., Ruziyev Sh.F, Kadirov X.I. Разработка технологии производства ингибиторов коррозии на основе смеси алкилимидозолинов [Development of corrosion inhibitor production technology based on a mixture of alkilimidosolins]. Universum: texnicheskiye nauki: 2025, 2(131). (In Russ.) Available at: URL: https://7universum.com/ru/tech/archive/item/19392

Solop G.R. Karbo- i geterosiklicheskiye ingibitori korrozii neftyanogo oborudovaniya [Carbo- and heterocyclic corrosion inhibitors of oil equipment] Bashkirskiy ximicheskiy jurnal . (In Russ.) 2015, 4, 39 - 45.

Usmonova Y., Kadirov B., Kamilov O., Davlyatova Z., Kadirov Kh., Cherkasova E. Modification of composition of salinity inhibitors based on organophosphonates and acrylic acid. Technical science and innovation” the science journal. 2020, 3 (05), 9-17.

Usmonova Yu., Davlyatova Z., Kadirov X.I. Polucheniye etilendiamina na osnove otrabotannogo monoetanolamina [Obtaining ethylenediamine based on spent monoethanolamine]. Universum: Texnicheskiye nauki. 2021, 9(90) (In Russ.) 40-45. DOI:10.32743/UniTech.2021.90.9.12250

Petrova V.Ye. Sintez i svoystva proizvodnix alkilimidazolinov [Synthesis and properties of alkylimidazoline derivatives] Vestnik TvGU Seriya Ximiya. 2014, (1), 36-43.

S. L. Vulfovich, O. V. Akchurina, A. N. Lobov, N. A. Sergeyeva, A. G. Telin, L. V. Spirixin, V. A. Dokichev. Kataliticheskoye vzaimodeystviye rapsovogo masla s 2-[(2-aminoetil)amino]etanolom v prisutstvii kationita KU-2x8 i NaOH [Catalytic interaction of rapeseed oil with 2-[ (2-aminoethyl) amino]ethanol in the presence of KU-2x8 cation exchanger and NaOH]. Bashkirskiy ximicheskiy jurnal. 2022. Tom 29. №3, 68-77. DOI:10.17122/bcj-2022-3-68-77.

Xudoleyeva Ye.S., Gurbanova L.V., Gunkin V.M. Sposob polucheniya alkilimidazolina [Method of producing alkylimidazoline] Patent RU, 2765948, 2021.

Valyuga V.V. Noviye podxodi k sintezu azotistix geterosiklicheskix soyedineniy s pomoshyu alifaticheskix aminov i nitrosoyedineniy, aktivirovannix fosfornimi kislotami. Diss. dokt.texn.nauk. [New approaches to the synthesis of nitrogen heterocyclic compounds using aliphatic amines and nitro compounds activated by phosphoric acids]. Stavropol, 2022. 60-69.

Kadirov K.I, Turabdjanov S. M. Synthesis of zincate-oxyethenediphosponic acid and the comparative results applying as scale inhibitors. Europaische Fachhochschule. European Applied Sciences. ISSN 2195-2183. #6 – 2015, 66-69.

Petrova V.E. Obtaining Functionally Substituted Imidazoline Derivatives. Chem Bio. 2014;2:45–83. Search in Google Scholar 2022, 16-18. DOI.org/10.1515/hc-2022-0173

Monika G, Chander M. Development of drugs based on imidazole and benzimidazole bioactive heterocycles: recent advances and future directions. Med Chem Res. 2016, 25, 173–210.

Edwards A. et al. Mechanistic studies of the corrosion inhibitor oleic imidazoline. Corrosion Science. 1994, vol. 36. №. 2, 315-325.

Durnie W., Gough M. Characterization, Isolation and Performance Characteristics of Imidazolines: Part II Development of Structure-Activity Relationships. Nace corrosion. 2003, 36.

Khan S., Quraishi M.A. Synergistic effect of potassium iodide on inhibitive performance of thiadiazoles during corrosion of mild steel in 20% sulfuric acid //Arabian Journal for Science and Engineering. – 2010. – Vol. 35. – №. 1. – P. 71-81.

Jiang X., Zheng Y.G., Ke W. Effect of flow velocity and entrained sand on inhibition performances of two inhibitors for CO2 corrosion of N80 steel in 3% NaCl solution. Corrosion science. 2005, vol. 47. №. 11, 2636-2658.

Liu X., Okafor P.C., Zheng Y.G. The inhibition of CO2 corrosion of N80 mild steel in single liquid phase and liquid/particle two-phase flow by aminoethyl imidazoline derivatives. Corrosion Science. 2009, vol. 51. №. 4, 744-751.

Sotelo-Mazon O. et al. Corrosion protection of 1018 carbon steel using an avocado oil-based inhibitor. Green Chemistry Letters and Reviews. 2019, vol. 12. №. 3, 255-270.

Usmanova Y.Sh., Davlyatova Z.M., Rakhimov K.N., Khamidjonov A.A., A. Ikramov. [Corrosion inhibitor by heterocyclic fragments] 1 st International scientific Conference"Modern Materials Science: Topical Issues, Achievements and Innovations" Tashkent, 2022, 663-671.

Usmonova Yu.Sh., Davlyatova Z.M., Kadirov X.I. [Sintez i primeneniye ingibitorov korrozii na osnove proizvodnix imidozolinov] “Innovasionniye podxodi k razvitiyu obrazovatelno-proizvodstvennogo klastera v neftegazovoy otrasli” materiali mejdunarodnoy konferensii [Materials of the international conference "Innovative approaches to the development of educational and production clusters in the oil and gas industry] Tashkent, 2022, 72-73.

Usmanova Y.Sh., Davlyatova Z.M., Rakhimov K.N., Khamidjonov A.A., A.Ikramov. Corrosion inhibitor by heterocyclic fragments. “Innovasionniye podxodi k razvitiyu obrazovatelno-proizvodstvennogo klastera v neftegazovoy otrasli” materiali mejdunarodnoy konferensii [Materials of the international conference "Innovative approaches to the development of educational and production clusters in the oil and gas industry] Tashkent, 2022, 228-229.

Bazanov D. R. 2,4,5-Triarilimidazolini: sintez, reaksionnaya sposobnost i biologicheskaya aktivnost. Diss. kand.texn.nauk. [2,4,5-Triarylimidazolines: synthesis, reactivity and biological activity.] Moskva, 2022. 36-40

Shi-Fa Wang, Takeshi Furuno, Zhi Cheng. Synthesis of 1-hydroxyethyl-2-alkyl-2-imidazoline and its derivative sulfonate amphoteric surfactant from tall oil fatty acid. College of Chemical Engineering of Forest Products. Сhina, 2020, 371-376. DOI:10.1007/s10086-002-0476-8

Michael W. Anderson, Raymond C.F. Jones, John Saunders. Imidazolines in synthesis, I: lithio imidazolines-formation and C-alkylation. Vol. 22, Issue 3, 2021, 261-264. https://doi.org/10.1016/0040-4039(81)80071-8

Petrov N.A. [Kationoaktivniye PAV effektivniye ingibitori v texnologicheskix prosessax neftegazovoy promishlennosti] Neftegazovoye delo, 2021, 2. (In Russ.) Available at: http://www.vipstd.ru/gim/content/view/90/278/). (accessed 22.05.2021)

Yusupov D., Batirov B.B., Pak V.V., Keremeskaya L.V., Fayziyev Sh.R. Razrabotka i issledovaniye svoystv novix ingibitorov korrozii na baze vtorichnix materialov OAO “Navoiazot” [Development and study of the properties of new corrosion inhibitors based on secondary materials of JSC "Navoiazot"] Ximicheskaya texnologiya. Kontrol i upravleniye. 2007, 6, (In Russ.) 8-12.

Yusupov D., Tursunov M.A., Xamrayev B.N. Razrabotka novix reagentov dlya dobichi nefti i gaza [Development of new reagents for obtaining oil and gas.] Ximicheskaya texnologiya. Kontrol i upravleniye. 2007, 1, (In Russ.) 38-39.

R.A. Raximkulov. Razrabotka texnologii proizvodstva ingibitorov korrozii na osnove aldegidov i aminov. Diss. kand.texn.nauk. [Development of a technology for the production of corrosion inhibitors based on aldehydes and amines] Ufa, 2005.171.

Majer Je.A. Effektivnaya praktika glubokoy pererabotki gazovogo syr'ya v khimicheskuyu produktsiyu na predpriyatiyakh OAO “SIBUR Holding” i ispol'zuemye tekhnologicheskie protsessy [Effective practice of deep processing of gas raw materials into chemical products at the enterprises of JSC SIBUR Holding and the technological processes used]. Tomsk State University Publ., 2014, 476. References

Yuklab olishlar

Nashr qilingan

2026-04-17