THERMAL-OXIDATIVE PYROLYSIS OF WASTE TIRES: PRODUCT CHARACTERIZATION AND POTENTIAL FOR RESOURCE RECOVERY AND BITUMEN MODIFICATION
DOI:
https://doi.org/10.5281/zenodo.19629947Keywords:
gas composition, resource recovery, bitumen modificationAbstract
This study investigates the thermal-oxidative pyrolysis of waste automobile tires as a route for converting secondary raw materials into valuable products. The process was carried out at 550 °C in a batch reactor, yielding gas, liquid, and solid fractions. The gas phase was found to be rich in combustible components, indicating its potential for energy recovery within the process. The liquid fraction exhibited properties suitable for further refining into fuel or chemical feedstocks, while the solid residue represented a carbon-containing material with potential application as a filler in polymer systems. Thermal analysis revealed that the degradation of tire rubber proceeds in two main stages, corresponding to devulcanization and subsequent decomposition of the carbon structure. These transformations govern the formation and distribution of pyrolysis products. The results confirm that pyrolysis of waste tires is an efficient and environmentally sound approach for waste management, offering a viable pathway for resource recovery and the production of value-added materials, including modifiers for bitumen and polymer composites.
References
A. Quek and R. Balasubramanian, “Liquefaction of waste tires by pyrolysis for oil and chemicals—A review,” J. Anal. Appl. Pyrolysis, vol. 101, pp. 1–16, 2013. https://doi.org/10.1016/j.jaap.2013.02.016
S. Williams, “Pyrolysis of waste tyres: A review,” Waste Management, vol. 33, pp. 1714–1728, 2013. https://doi.org/10.1016/j.wasman.2013.05.003
M. A. Islam, A. Haniu, and M. R. Beg, “Liquid fuels and chemicals from pyrolysis of waste tires,” Energy Conversion and Management, vol. 49, pp. 247–256, 2008. https://doi.org/10.1016/j.enconman.2007.06.031
J. D. Martínez et al., “Waste tyre pyrolysis – A review,” Renewable and Sustainable Energy Reviews, vol. 23, pp. 179–213, 2013. https://doi.org/10.1016/j.rser.2013.02.038
A. Lopez et al., “Pyrolysis of waste tyres: Influence of operating conditions,” Journal of Analytical and Applied Pyrolysis, vol. 73, pp. 285–298, 2005. https://doi.org/10.1016/j.jaap.2005.03.002
J. A. Conesa et al., “Thermogravimetric analysis of tyre decomposition,” Journal of Analytical and Applied Pyrolysis, vol. 58–59, pp. 585–597, 2001. https://doi.org/10.1016/S0165-2370(00)00180-3
В.Н. Жураев, Э.Э. Машаев, М.Д. Вапаев, А.С. Ибадуллаев, “Модификация битума для получения тепло-морозостойких дорожных композиций,” Узбекский химический журнал, №4, с. 40–46, 2019. [In Russian]
R.M. Mirzaakbarov et al., “Study of the physicochemical properties of worn automobile tires for use as modified bitumen components,” Science and Innovation, vol. 5, no. 3, pp. 34–41, 2026. https://doi.org/10.5281/zenodo.18998067
R.M. Mirzaakbarov et al., “Development of a technological line for the production of polymer-bitumen compositions,” Development of Science, vol. 2, no. 3, pp. 286–295, 2026.
J. Scheirs and W. Kaminsky, Feedstock Recycling and Pyrolysis of Waste Plastics, Wiley, 2006. https://doi.org/10.1002/0470021543